You have to login with your ACS ID befor you can login with your Mendeley account. Measuring Structural and Electronic Effects on Keto–Enol Equilibrium in 1,3-Dicarbonyl Compounds. The organic compound ethyl acetoacetate is a colorless liquid with a molecular weight of 130.143 g/mol, which may cause adverse health effects if inhaled. Please reconnect. Find more information about Crossref citation counts. You’ve supercharged your research process with ACS and Mendeley! Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Tautomerism of bis(2,4-benzyloxy)-6-(5H)-one-1,3,5-triazine: A combined crystallographic and quantum-chemical investigation. The keto–enol equilibrium constants of acetylacetone, ethyl acetoacetate and ethyl benzoylacetate in water at 25 °C were determined by studying the influence of surfactants on their UV-visible spectra. The prefix “et” refers to ethyl. This article is cited by Kuangsen Sung, Ru-Rong Wu, Shu-Yi Sun. DOI: 10.1021/acs.jchemed.5b00170. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. We will be doing this with various 1,3-dicarbonyl compounds in several different solvents. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Sherri C. YoungKyle T. Smith James W. DeBlasioChristian S. Hamann. An experiment designed to illustrate the determination of equilibrium constants of chemical reactions. protons while the keto methylene has only two protons; the weighting factor, in this case, is 2/3. 5 publications. Keto-enol tautomerism of β-ketoamides and characterization of a sterically crowded α-amido-β-ketoamide. The keno–enol equilibrium constants of acetylacetone, ethyl acetoacetate and ethyl benzoylacetate in water at 25 °C are determined by studying the influence of surfactants on their UV–VIS spectra, following the method applied to benzoylacetone published recently. https://doi.org/10.1021/acs.jchemed.5b00170, https://doi.org/10.1021/bk-2016-1221.ch009, https://doi.org/10.1134/S0036024420060357, https://doi.org/10.1007/s11224-006-9058-5. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Your Mendeley pairing has expired. Keto is a safe and healthy way to benefit overall health, lose excess weight, and burn fat while maintaining sustained energy and steady blood sugar levels. Determination of the equilibrium constant for keto-enol tautomerism of ethyl acetoacetate. Sherri C. YoungKyle T. Smith James W. DeBlasioChristian S. Hamann. These metrics are regularly updated to reflect usage leading up to the last few days. Acetoacetate vs. Ethyl Acetoacetate. Characteristic Features of the Gas Chromatographic Separation of Tautomers of Ethyl Acetoacetate. However, the keto-enol equilibrium is slow on an NMR time scale and so can be measured using proton (1H) NMR. Utilizing NMR To Study Structure and Equilibrium in the Organic Chemistry Laboratory. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information about Crossref citation counts. Measuring Structural and Electronic Effects on Keto–Enol Equilibrium in 1,3-Dicarbonyl Compounds. K. Srinivas, Sanyasi Sitha, B. Sridhar, V. Jayathirtha Rao, K. Bhanuprakash, K. Ravikumar. … Find more information on the Altmetric Attention Score and how the score is calculated. Get article recommendations from ACS based on references in your Mendeley library. Figure 2: Full 1H NMR spectrum of ethyl acetoacetate. Journal of Chemical Education 2016, 93 (4) , 790-794. the Altmetric Attention Score and how the score is calculated. Acetoacetic ester (ethyl acetoacetate) is an extremely useful molecule that can be used to make ketones and other molecules. Several dicarbonyl compounds that can be used include acetyl acetone (1), dimedone (3), ethyl acetoacetate (4) and ethyl 4,4,4-trifluoroacetate (5). These measured equilibrium constants were used to obtain the reactivity of the ketones towards several nitrosating agents.
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