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In the Fischer-Hepp rearrangement aromatic 4-nitroso-anilines are prepared from the corresponding nitrosamines. nitroso group: ChEBI ID CHEBI:35801: Stars This entity has been manually annotated by the ChEBI Team. (. Page ID 40734; Contributed by Gamini Gunawardena; Associate Professor (Chemistry) at Utah Valley University; Table of contents . [ "article:topic", "authorname:ggunawardena", "showtoc:no" ]. Nitroso compounds can be prepared by the reduction of nitro compounds or by the oxidation of hydroxylamines. Stars This entity has been manually annotated by the ChEBI Team. Your browser does not support JavaScript. Find compounds which contain this structure, Find compounds which resemble this structure, European Molecular The following resonance-stabilized cation is called the nitrosyl cation. Biology Laboratory | Terms of use. With an accout for my.chemeurope.com you can always see everything at a glance – and you can configure your own website and individual newsletter. Biology Laboratory, nitroso compound The syntheses of the title compounds demonstrate a privileged introduction of a nitroso (and a hydroxyl via the Baudisch reaction) group to an aromatic ring. The nitrogen atom can be easily inserted into organic molecules in its higher oxidation state as a nitro group from which nitroso or amino derivatives can be obtained by a reductive process. Nitroso refers to a functional group in organic chemistry which has the general formula RNO. A good example is (CH3)3CNO, known formally as 2-methyl-2-nitrosopropane, or t-BuNO, which is prepared by the following sequence:[1]. This service is an Elixir Core Data Resource. Unless otherwise noted, LibreTexts content is licensed by CC BY-NC-SA 3.0. On the other hand, modern synthetic methods allow a direct introduction of the amino moiety through reductive or electrophilic amination. Categories: Functional groups | Oxygen compounds | Nitrogen compounds. © 1997-2020 LUMITOS AG, All rights reserved, https://www.chemeurope.com/en/encyclopedia/Nitroso.html, Your browser is not current. Find out more about the company LUMITOS and our team. A new method of calculating the Mulliken net charges of the nitro group, QNO2, to assess impact sensitivities for nitro compounds is established. Contributors and Attributions; The following resonance-stabilized cation is called the nitrosyl cation. Watch the recordings here on Youtube! Contributors and Attributions. 80 − 81 °C. The LibreTexts libraries are Powered by MindTouch® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. For more information contact us at info@libretexts.org or check out our status page at https://status.libretexts.org. Missed the LibreFest? 1SD, UK     +44 (0)1223 49 44 44, Copyright © EMBL-EBI 2018 | EBI is an outstation of the European Molecular These complexes first appeared in the literature as early as 1939, and a range of applications has subsequently been published. This entity has been manually annotated by the ChEBI Team. EMBL-EBI, Wellcome Genome Campus, Hinxton, Cambridgeshire, CB10 Legal. To use all the functions on Chemie.DE please activate JavaScript. Another named reaction involving a nitroso compound is the Barton reaction. Read what you need to know about our industry portal chemeurope.com. (CH3)3CNO is blue and exists in solution in equilibrium with its dimer, which is colorless, m.p. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE. Find out how LUMITOS supports you with online marketing. O-Alkylation of N-nitroso-N-phenylhydroxylamine ammonium salt (cupferron) was ... Cupferron was administered in the feed, at either of two concentrations, to groups of 49 or 50 male and 50 female animals of each species. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. Nitroso refers to a functional group in organic chemistry which has the general formula RNO. To use all functions of this page, please activate cookies in your browser. Gamini Gunawardena from the OChemPal site (Utah Valley … S-nitroso-N-acetyl-D-penicillamine: ChEBI ID CHEBI:77702: ChEBI ASCII Name S-nitroso-N-acetyl-D-penicillamine: Definition A nitroso compound that is N-acetyl-D-penicillamine in which the sulfanyl hydrogen is replaced by a nitroso group. Nitroso Group; N-nitrosamine; Donate. Have questions or comments? see also nitroso group.

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